축산현장에서 발생된 암모니아 기체의 흡착기반 회수 동향 및 향후 전략 = Trend and Future Strategy of Ammonia Gas Recovery based on Adsorption from Livestock Fields

국문 초록 (Abstract)

본 연구에서는 축산 분야에서 배출되는 암모니아를 효과적으로 회수할 수 있는 흡착기술의 연구개발 동향 및 향후 전략에 대해 논의하였다. 적절한 암모니아 흡착제는 표면의 산성기나 수소결합기를 가지며 높은 비표면적과 암모니아 흡착에 적절한 표면구조를 지니어야한다. 일반적인 암모니아 흡착제로는 활성탄이나 제올라이트 등의 광물질이 널리 쓰이나 대체로 흡착효과가 낮아 표면 개질 등을 통한 개선이 필요하다. 일례로 금속염화물이 다공성 흡착제에 포함되었을 때, 활성탄이나 제올라이트의 표면에 흡착 시보다 암모니아 흡착량이더 증가하는 것으로 알려져 있다. 최근에는 MOFs (Metal-Organic Frameworks)나 POPs (Porous Organic Polymers) 같은 새로운 종류의흡착제가 개발 및 적용되고 있으며 조절가능한 높은 비표면적과 다공성으로 매우 높은 암모니아 흡착용량을 보였다. 그 외에 프러시안 블루가 높은 암모니아 흡탈착성능 및 선택성을 보였는데. 이는 축산폐기물 배출 암모니아 회수에 관련하여 상대적으로 유리한 측면으로 보인다. 향후 다양한 흡착제를 이용, 축산현장에 맞는 조건에서 암모니아 흡탈착 효율 및 순도를 평가하는 연구가 더 활발히 진행되어야 할것이다. 아울러 암모니아 회수를 극대화하기 위한 효과적인 전/후처리 공정도 병행되어야 한다.

다국어 초록 (Multilingual Abstract)

This study discussed the trend and future strategy of adsorption technology R&D to effectively recover ammonia emitted from the livestock fields. A proper ammonia adsorbent should incorporate acidic or hydrogen bonding functional groups on the surface, as well as a high specific surface area and a good surface structure appropriate for ammonia adsorption. Activated carbon and minerals such as zeolite have widely been used as ammonia adsorbents, but their adsorption effects are generally low, so any improvement through surface modification should be necessary. For example, incorporation of metal chloride included in a porous adsorbent can promote ammonia adsorption effectiveness. Recently, new types of adsorbents such as MOFs (Metal-Organic Frameworks) and POPs (Porous Organic Polymers) have been developed and utilized. They have shown very high ammonia adsorption capacity because of adjustable and high specific surface area and porosity. In addition, Prussian Blue exhibited high ammonia adsorption and desorption performance and selectivity. This looks relatively advantageous in relation to the recovery of ammonia from livestock waste discharge. In the future, further research should be made to evaluate ammonia adsorption/desorption efficiency and purity using various adsorbents under conditions suitable for livestock sites.
Also, effective pre- and/or post-treatment processes should be integrated to maximize ammonia recovery.

참고문헌 (Reference)

• 1 김기연 ; 박재범 ; 김치년 ; 이경종, "돈사 작업장 유형에 따른 암모니아와 황화수소의 실내농도 및 발생량에 관한 현장 조사" 한국산업보건학회 16 (16): 36-43, 2006
• 2 김민석 ; 구남인 ; 김정규, "국내외 가축분뇨 퇴액비 이용 분야 암모니아 배출량 인벤토리 비교 연구" 한국환경생물학회 38 (38): 71-81, 2020
• 3 Khabzina, Y., "Unravelling ammonia adsorption mechanisms of adsorbents in humid conditions" 265 : 143-148, 2018
• 4 Tao, C., "Tunable selectivity of radical generation over TiO2 for photocatalysis" 214 : 7-, 2020
• 5 Lucero, J. M., "Tunability of ammonia adsorption over NaP zeolite" 324 : 111288-, 2021
• 6 Takahashi, A., "Trace Ammonia Removal from Air by Selective Adsorbents Reusable with Water" 12 (12): 15115-15119, 2020
• 7 Cho, S. -B., "The study on investigation of factors and reduction for odor generating substrates from hog farm, NIAS Grant(No. PJ008606)" National Institute of Animal Science 2015
• 8 Poling, B. E., "The properties of gases and liquids" McGraw-Hill Education 2001
• 9 Szymula, A., "The Use of Natural Sorbents to Reduce Ammonia Emissions from Cattle Faeces" 11 (11): 2543-, 2021
• 10 Hanson, D., "The NH3 mass accom"modation coefficient for uptake onto sulfuric acid colutions" 107 (107): 2199-2208, 2003
• 11 Pandey, B., "Technologies to recover nitrogen from livestock manure-A review" 784 : 147098-, 2021
• 12 Kim, S. -D., "System development of ammonia deaeration and adsorption/de sorption, Final report of Project(2014000150007)" Korea Environmental Industry & Technology Instituter 2017
• 13 Yang, Y., "Surface pore engineering of covalent organic frameworks for ammonia capture through synergistic multivariate and open metal site approaches" 4 (4): 748-754, 2018
• 14 Luo, L., "Superhigh and reversible NH3 uptake of cobaltous thiocyanate func"tionalized porous poly ionic liquids through competitive and cooperative interactions" 427 : 131638-, 2022
• 15 Hao, J. N., "Simultaneous determination of indoor ammonia pollution and its biological metabolite in the human body with a recyclable nanocrystalline lanthanide functionalized MOF" 8 (8): 2881-2886, 2016
• 16 Matito-Martos, I., "Role of hydrogen bonding in the capture and storage of ammonia in zeolites" 387 : 124062-, 2020
• 17 Susaya, J., "Removal of gaseous NH3 by water as a sorptive medium: the role of water volume and absorption time" 19 (19): 745-750, 2010
• 18 Gupta, V. K., "Removal of ammonium ions from wastewater a short rev iew in development of efficient methods" 1 (1): 149-158, 2015
• 19 Dong, Y., "Removal of ammonia nitrogen from wastewater : A review" 62 (62): 1767-1778, 2019
• 20 Zhang, F., "Removal of ammonia and hydrogen sulfide from livestock farm by copper modified activated carbon" 22 (22): 165-172, 2020
• 21 Kinidi, L., "Recent development in ammonia stripping process for industrial wastewater treatment" 14-, 2018
• 22 Cao, Z., "Porous strontium chloride scaffolded by graphene networks as ammonia carriers" 31 (31): 2008505-, 2021
• 23 Lee, M. -K., "Policy improvement to reduce odor and environmental pollution in agricultural and livestock industry, KREI basic research report R896 Research document 1" Korea Rural Economic Institute 1-177, 2019
• 24 Cheema, I. I., "Operating envelope of Haber-Bosch process design for power-to-ammonia" 8 (8): 34926-34936, 2018
• 25 Yang, C., "One-step template-free synthesis of 3D functionalized flower-like boron nitride nanosheets for NH3 and CO2 adsorption" 10 (10): 10979-10985, 2018
• 26 Rada-Ariza, A. M., "Nitrification by microalgal-bacterial consortia for ammonium removal in flat panel sequencing batch photo-bioreactors" 245 : 81-89, 2017
• 27 Seredych, M., "Moisture insensitive adsorption of ammonia on resorcinol-formaldehyde resins" 305 : 96-104, 2016
• 28 Zhao, X., "Metal-organic frameworks for separation" 30 (30): 1705189-, 2018
• 29 Vikrant, K., "Metal"organic frameworks(MOFs) : potential and challenges for capture and abatement of ammonia" 5 (5): 22877-22896, 2017
• 30 Vikrant, K., "Metal"organic frameworks(MOFs) : potential and challenges for capture and abatement of ammonia" 5 (5): 22877-22896, 2017
• 31 Korea Environmental Institute, "Management Strategies to Reduce PM-2.5 Emission: Emphasis-Ammonia" KEI 1-89, 2017
• 32 Rieth, A. J., "Kinetic stability of metal-organic frameworks for corrosive and coordinating gas capture" 4 (4): 708-725, 2019
• 33 Takahashi, A., "Historical pigment exhibiting ammonia gas capture beyond standard adsorbents with adsorption sites of two kinds" 138 (138): 6376-6379, 2016
• 34 Ma, Z., "Highlighting unique function of immobilized superoxide on TiO2 for selective photocatalytic degradation" 238 : 116402-, 2020
• 35 Kim, D. -W., "High ammonia uptake of a metal-organic framework adsorbent in a wide pressure range" 59 (59): 22531-22536, 2020
• 36 Jafari, M. J., "Experimental optimization of a spray tower for ammonia removal" 9 : 783-790, 2018
• 37 Jasuja, H., "Evaluation of MOFs for air purification and air quality control applications : Ammonia removal from air" 124 : 118-124, 2015
• 38 Qajar, A., "Enhanced ammonia adsorption on functionalized nanoporous carbons" 218 : 15-23, 2015
• 39 DeCoste, J. B., "Enhanced aging properties of HKUST-1 in hydrophobic mixed-matrix membranes for ammonia adsorption" 7 (7): 2711-2716, 2016
• 40 Wang, Y. C., "Emissions, measurement, and control of odor in livestock farms: A review" 776 : 145735-, 2021
• 41 Yang, H., "Effect of boron doping on graphene oxide for ammonia adsorption" 3 (3): 794-797, 2017
• 42 Rieth, A. J., "Controlled gas uptake in metal-organic frameworks with record ammonia sorption" 140 (140): 3461-3466, 2018
• 43 Helminen, J., "Comparison of Sorbents and Isotherm Models for NH3-Gas Separation by Adsorption" 46 (46): 1541-1555, 2000
• 44 Moribe, S., "Ammonia capture within isoreticular metal–organic frameworks with rod secondary building units" 1 (1): 476-480, 2019
• 45 Maia, G. D. N., "Ammonia biofiltration and nitrous oxide generation during the start-up of gas-phase compost biofilters" 46 : 659-664, 2012
• 46 Nijem, N., "Ammonia adsorption and co-adsorption with water in HKUST-1 : Spectroscopic evidence for cooperative interactions" 119 (119): 24781-24788, 2015
• 47 Mochizuki, T., "Adsorption behaviors of ammonia and hydrogen sulfide on activated carbon prepared from petroleum coke by KOH chemical activation" 144 : 164-169, 2016
• 48 Han, B., "Adsorbent materials for ammonium and ammonia removal : A review" 283 : 124611-, 2021
• 49 Bandosz, T. J., "Activated carbon surfaces in environmental remediation" Elsevier 2006
• 50 Han, J., "A study to establish the 2nd integrated malodor prevention policy" National Institute of Environmental Research 2018
• 51 Lee Sang-Hun ; Bae Sunghyun, "A strategy for ammonia odor monitoring, prediction, and reduction from livestock manure wastes in Korea: a short review" 한국자원공학회 25 (25): 35-43, 2022
• 52 Tian, X., "A record ammonia adsorption by calcium chloride confined in covalent organic frameworks" 58 (58): 1151-1154, 2022
• 53 Chen, D. L., "A new cost-effective method to mitigate ammonia loss from intensive cattle feedlots : Application of lignite" 5 (5): 16689-, 2015
• 54 Zhang, J., "A mini-review on NH3 separation technologies : recent advances and future directions" 36 (36): 14516-14533, 2022
• 55 Lee, J. W., "A microporous amic acid polymer for enhanced ammonia capture" 9 (9): 33504-33510, 2017
• 56 Ye, Y. Y., "A critical review on ammonium recovery from wastewater for sustainable wastewater management" 268 : 749-758, 2018